## Abstract The carbon kinetic isotope effect in the reaction of CH~4~ with OH has an experimentally measured value of 1.003. The measurement was performed using a static system in which the source of OH was the gasβphase photolysis of H~2~O~2~ with ultraviolet light produced by a highβpressure mer
Kinetic isotope effect in the chemiluminescent oxidation of acridan by dibenzoylperoxide
β Scribed by Steen Steenken
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 221 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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Rates of oxidation of XCOO-(X = H, D) by Brz in acid aqueous media were measured between 274 and 332 K. The derived Arrhenius parameters for both reactions log k ~( M -l S-') = (11.81 f 0.10) -(14.33 f 0.13)/0 log ~D ( M -' S-') = (13.77 f 0.13) -(17.62 f 0.04)/0 where 0 = 4.575T X kcal/mol, with (
The electro-oxidation of a series of selectively deuterated alcohols (Zpropanol, 1,2-butanediol, l+butanediol and 2,fbutanediol) at a polycrystalline gold electrode in alkaline solutions was studied with cyclic voltammetry. Results were evaluated with respect to the mechanism of the electro-oxidatio