A relative rate approach has , been used to measure the reactivity of CF,O radicals towards ozone. Using k(CFaO+NOa)=2,7x IO-" cm' molecule-' s-' as the referencereactioqanupperlimit ofk(CF,O+Os) 63~ 10-'4cmSmolecule-' was determined at 295 K and 700 Torr of O2 diluent. The implications for the atmo
Kinetic investigation of the elemental reactions of oxygen atoms in the gas phase by ESR III. The reaction O(3P)+O3=2O2
β Scribed by V. P. Balakhnin; V. I. Egorov
- Publisher
- Springer US
- Year
- 1969
- Tongue
- English
- Weight
- 233 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1573-8582
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The gas-phase, ion molecule reaction between C,O:' and C,O, has been studied by both double-focusing and ion trap mass spectrometry, rationalized by the formation of a dimeric, odd electron cation IC6041+" which decomposes extensively through sequential CO losses giving rise to IC,O,l+. and IC,O,l+'
The bimolecular rate constant for the reaction Cl + 03 -Cl0 + O2 is measured over the temperature range 210 to 360 K in it dischare flow system using Cl nfom rcsonzncc fluorescence at 134-72 nm to monitor the decay of Cl under pseudo fist order conditions. Results, expressed in the form k, = (2.35 i
## Abstract The kinetics of the reaction of O(^3^__P__) atoms with acetone were investigated using fast flow methods. The reaction was studied over a temperature range of 298 to 478Β°K. The specific rate constant obtained was (1.9 Β± 0.4) Γ 10^12^ exp(β5040 Β± 180/1.987 __T__) cm^3^/molΒ·sec. The obser
## Abstract The reaction of O(^3^__P__) atoms with isobutane has been studied by using the dischargeβflow system described previously [1]. The rate constant was measured from determinations of the isobutane concentration in the presence of an excess of O atoms and is given by __k__~1~ = (7.9 Β± 1.4)