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On the gas-phase reaction of C3O2+. with C3O2

✍ Scribed by L. Pandolfo; G. Paiaro; À. Somogyi; S. Catinella; P. Traldi

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
561 KB
Volume
29
Category
Article
ISSN
1076-5174

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✦ Synopsis

The gas-phase, ion molecule reaction between C,O:' and C,O, has been studied by both double-focusing and ion trap mass spectrometry, rationalized by the formation of a dimeric, odd electron cation IC6041+" which decomposes extensively through sequential CO losses giving rise to IC,O,l+. and IC,O,l+' ions. The thermodynamics of this process have been investigated by means of ab initio calculation performed on the above species using different basis sets (STO-3G, 3-21G and 6-31G*).

JNTRODUCTJON

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