Solvent dynamics-modified RRKM theory in
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R.A. Marcus
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Article
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1995
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Elsevier Science
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English
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Kramers and RRKM theories are used to formulate a solvent dynamics-modified treatment of unimolecular reaction rates in clusters. The canonical Kramers' description is modified so as to apply to microcanonical systems. An entropic gradient, arising from all coordinates but the reaction coordinate q,