Isolation and x-ray crystal structures of the mononuclear cuprates [CuMe2]-, [CuPh2]-, and [Cu(Br)CH(SiMe3)2]-
β Scribed by Hope, Hakon; Olmstead, Marilyn M.; Power, Philip P.; Sandell, Janet; Xu, Xiaojie
- Book ID
- 127234840
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 287 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0002-7863
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## Synthesis and X-ray Crystal Structure Analysis of C U ~( C H ~C H ~C O O ) \* ( O P P ~~) ~ The complex of [ C U ( C H ~C H C O O ) ~( O P ~~) ] ~ has been synthesized and its X-ray crystal structure determined at room temperature, M = 975.96, tetragonal, space group: I41/a(#88), Dx = 1.39 g/ c
The hydrothermal reactions of CuBr 2 , CuBr, and ethylenediamine have resulted in the synthesis of two new compounds. [Cu(H 2 NCH 2 CH 2 NH 2 ) 2 ] [{Cu 2 Br 4 }] has a two-dimensional sheet structure while [Cu(H 2 NCH 2 CH 2 NH 2 ) 2 ] [{Cu 5 Br 7 }] crystallizes as a three-dimensional network. Bot