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Synthesis and X-ray Crystal Structure of a Novel Zinc “Ate Complex”, [Li(TMEDA)] 2 Zn(CH 2 SiMe 2 SiMe 2 CH 2 ) 2

✍ Scribed by Wyrwa, Ralf; Fröhlich, Hans-Otto; Görls, Helmar


Book ID
127033827
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
88 KB
Volume
15
Category
Article
ISSN
0276-7333

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✍ Westerhausen, Matthias ;Wieneke, Michael ;Rademacher, Bernd B. ;Schwarz, Wolfgan 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 772 KB

## Abstract The reaction of lithium phenyl(trimethylsilyl)methanide with phenyl(trimethylsilyl)methylzinc chloride‐tmeda in the presence of tmeda yields the addition product, a bis(tmeda)‐lithium dialkylchlorozincate. The elimination of lithium chloride leads to the formation of a tmeda adduct of b