Phosphinoalkylsilyl Complexes. 12. Stereochemistry of the Tridentate Bis(diphenylphosphinopropyl)silyl (biPSi) Framework: Complexation That Introduces “Face Discrimination” at Coordinatively Unsaturated Metal Centers. X-ray Crystal and Molecular Structures of Pt[SiMe(CH 2 CH 2 CH 2 PPh 2 ) 2 ]Cl, IrH[SiMe(CH 2 CH 2 CH 2 PPh 2 ) 2 ]Cl, and RuH[SiMe(CH 2 CH 2 CH 2 PPh 2 ) 2 ](CO) 21

✍ Scribed by Brost, Ron D.; Bruce, Gregg C.; Joslin, Frederick L.; Stobart, Stephen R.

• Book ID: 127191316
• Publisher: American Chemical Society
• Year: 1997
• Tongue: English
• Weight: 483 KB
• Volume: 16
• Category: Article
• ISSN: 0276-7333
• DOI: 10.1021/om970518k