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Synthesis and X-ray Crystal Structure Analysis of CU2(CH3CH2COO)4(OP)2

✍ Scribed by Li Jianmin; Zeng Huaqiang; Ke Yanxiong; Wang Quanming; Wu Xintao

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
264 KB
Volume
32
Category
Article
ISSN
0232-1300

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✦ Synopsis

Synthesis and X-ray

Crystal Structure Analysis of C U ~( C H ~C H ~C O O ) * ( O P P ~~) ~ The complex of [ C U ( C H ~C H C O O ) ~( O P ~~) ] ~ has been synthesized and its X-ray crystal structure determined at room temperature, M = 975.96, tetragonal, space group: I41/a(#88), Dx = 1.39 g/ cm3, The final R is 0.067 for 2087 independent observed reflections with 1 > &(I). The molecule has an inversion center on the middle of the Cu-Cu axis. The bond-length of the Cu-Cu is 2.61/ (2) A. The coordinate polyhedron of Cu corresponds to a tetragonal bipyramid. The angle of Cu-0-P is significantly smaller than that of its adducts [Cu(02CR)2L]2.

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