𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Is the CH2OH + O2→ CH2= O + HO2Reaction Barrierless? An Ab Initio Study on the Reaction Mechanism

✍ Scribed by Víctor M. Ramírez-Ramírez; Luis Serrano-Andrés; Ignacio Nebot-Gil


Publisher
Springer
Year
2006
Tongue
English
Weight
123 KB
Volume
116
Category
Article
ISSN
1432-2234

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Mechanism of the OH–propene–O2 reaction:
✍ Irina Díaz-Acosta; J. Raúl Alvarez-Idaboy; Annik Vivier-Bunge 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 172 KB 👁 2 views

The reaction of OH radicals with olefins is known to be important in atmospheric chemistry. From experimental data a global mechanism has been proposed, but the regioselectivity of the products is uncertain. In this work, the OH-propene-O 2 reaction has been studied with ab initio molecular orbital

Ab initio study of the OH + CH2O reactio
✍ Shucheng Xu; R. S. Zhu; M. C. Lin 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB 👁 2 views

## Abstract Kinetics for the reaction of OH radical with CH~2~O has been studied by single‐point calculations at the CCSD(T)/6‐311+G(3__df__, 2__p__) level based on the geometries optimized at the B3LYP/6‐311+G(3__df__, 2__p__) and CCSD/6‐311++G(__d__,__p__) levels. The rate constant for the reacti

The fast reaction of CH2OH with O2
✍ H.E. Radford 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 282 KB

The rate coefficient of the reaction CHzOH + 02 -HO2 + CH20. has been measured at 300 K by the LMR flow-tube method, and found to have the unexpectedly large value k = (2J) x 1O-'2 cm3 molecule-' s-I\_ This reaction. preceded by fiomenzafion, may be an important route for the oxidation of CHJO m the