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Reaction mechanism of the radical isomerization from CH3O to CH2OH in frozen methanol. An ab initio MO and RRKM study

โœ Scribed by Hiroto Tachikawa


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
365 KB
Volume
212
Category
Article
ISSN
0009-2614

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An alternative mechanism of BH2SH format
โœ Alexander M. Mebel; Djamaladdin G. Musaev; Keiji Morokuma ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 411 KB

An alternative mechanism of mercaptoborane, BH,SH, formation is proposed for the reaction of BzHs with SH2. It involves concerted elimination of BH3 and H2 from the H2SB2Hs complex and the highest energy on the pathway relative to SH, + B2H6 is 27.4 kcal/mol at MP4(SDTQ)/6-31 +G(2d, p)//MP2(FULL)/6\