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Iridium(III) catalyzed oxidation of cyclic ketones by cerium(IV)

โœ Scribed by Praveen K. Tandon; Alok K. Singh; Ramesh Baboo; Priy B. Dwivedi

Book ID
106546876
Publisher
Springer
Year
2004
Tongue
English
Weight
127 KB
Volume
29
Category
Article
ISSN
0340-4285

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Un-catalyzed and iridium(III) catalyzed
Un-catalyzed and iridium(III) catalyzed oxidation of p-methoxy benzaldehyde by cerium(IV)
โœ Praveen K. Tandon; Manisha Purwar; Satpal Singh; Nidhi Srivastava ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 389 KB

Apart from being an efficient catalyst in acidic medium iridium trichloride, was found to change order of the reaction with respect to cerium(IV) sulphate concentrations in the oxidation of p-methoxy benzaldehyde in aqueous acidic medium. Cerium(IV) and organic substrate form complex in the first eq