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Oxidation of cyclic ketones by cerium(IV) in presence of iridium(III) chloride

✍ Scribed by Praveen K. Tandon; Sumita Sahgal; Alok K. Singh; Santosh Kumar; Mamta Dhusia


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
310 KB
Volume
258
Category
Article
ISSN
1381-1169

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Apart from being an efficient catalyst in acidic medium iridium trichloride, was found to change order of the reaction with respect to cerium(IV) sulphate concentrations in the oxidation of p-methoxy benzaldehyde in aqueous acidic medium. Cerium(IV) and organic substrate form complex in the first eq

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The kinetics of the reaction between cyclopentanone and cyclohexanone with hexacyanoferrate(III) ion catalyzed by rhodium(III) chloride in alkaline medium has been investigated at four temperatures. The data show that the reaction follows first order kinetics with respect to hydroxide ion and cyclic