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Iridium(III) catalyzed oxidation of toluene and ethyl benzene by cerium(IV) in aqueous acidic medium

✍ Scribed by Praveen K. Tandon; Manish Srivastava; Santosh Kumar; Satpal Singh

Publisher: Elsevier Science
Year: 2009
Tongue: English
Weight: 371 KB
Volume: 304
Category: Article
ISSN: 1381-1169
DOI: 10.1016/j.molcata.2009.01.035

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Apart from being an efficient catalyst in acidic medium iridium trichloride, was found to change order of the reaction with respect to cerium(IV) sulphate concentrations in the oxidation of p-methoxy benzaldehyde in aqueous acidic medium. Cerium(IV) and organic substrate form complex in the first eq