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Rhodium(III) catalyzed oxidation of cyclic ketones by alkaline hexacyanoferrate(III)

โœ Scribed by Praveen K. Tandon; Mamta Dhusia


Book ID
106547516
Publisher
Springer
Year
2008
Tongue
English
Weight
310 KB
Volume
34
Category
Article
ISSN
0340-4285

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Oxidation of cyclic ketones by alkaline
โœ Praveen K. Tandon; Mamta Dhusia; Sumita Sahgal ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 440 KB

The kinetics of the reaction between cyclopentanone and cyclohexanone with hexacyanoferrate(III) ion catalyzed by rhodium(III) chloride in alkaline medium has been investigated at four temperatures. The data show that the reaction follows first order kinetics with respect to hydroxide ion and cyclic