Un-catalyzed oxidation of cyclic ketones by alkaline hexacyanoferrate(III) - Kinetic evidence for the formation of hydrates
โ Scribed by Tandon, Praveen K. ;Kumar, Santosh ;Singh, Alok K. ;Srivastava, Nidhi
- Book ID
- 106512881
- Publisher
- Springer
- Year
- 2008
- Tongue
- English
- Weight
- 141 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0133-1736
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๐ SIMILAR VOLUMES
The kinetics of the reaction between cyclopentanone and cyclohexanone with hexacyanoferrate(III) ion catalyzed by rhodium(III) chloride in alkaline medium has been investigated at four temperatures. The data show that the reaction follows first order kinetics with respect to hydroxide ion and cyclic
The kinetics of the oxidation of cyclopentanol, cyclohexanol, 2-methylcyclohexanol, and cycloheptanol by hexacyanoferrate(II1) ions in mild alkaline medium has been studied in the presence of traces of ruthenium(V1) = lO-?M at constant ionic strength (0.26M). The results suggest that the oxidation o