The kinetics of the reaction between cyclopentanone and cyclohexanone with hexacyanoferrate(III) ion catalyzed by rhodium(III) chloride in alkaline medium has been investigated at four temperatures. The data show that the reaction follows first order kinetics with respect to hydroxide ion and cyclic
Kinetics of the Ru(III) catalyzed oxidation of formaldehyde and acetaldehyde by alkaline hexacyanoferrate(III)
β Scribed by Anil K. Awasthi; Santosh K. Upadhyay
- Publisher
- Springer Vienna
- Year
- 1985
- Tongue
- English
- Weight
- 324 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0026-9247
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The kinetics of the oxidation of cyclopentanol, cyclohexanol, 2-methylcyclohexanol, and cycloheptanol by hexacyanoferrate(II1) ions in mild alkaline medium has been studied in the presence of traces of ruthenium(V1) = lO-?M at constant ionic strength (0.26M). The results suggest that the oxidation o
The kinetics of Ru(VI)-catalyzed oxidation of 2-propanol by hexacyanoferrate(III) was investigated in alkaline media using a spectrophotometric technique. The reaction shows first order in [Ru(VI)], a Michaelis-Menten-type dependence on [2-propanol], a fractional order in [Fe(CN) 3Γ 6 ] and a compli
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