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Investigations of the retention mechanism in gas—liquid partition chromatography

✍ Scribed by Z. Suprynowicz; A. Waksmundzki; W. Rudziński; J. Rayss

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
851 KB
Volume
91
Category
Article
ISSN
1873-3778

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✦ Synopsis

A new graphical method is proposed for estimating the retention mechanism in gas-liquid partition chromatographic (GLPC) systems in which adsorption phenomena occur. The proposed method enables the adsorption phenomena accompanying the bulk liquid solution to be investigated unequivocally from gas chromatographic data alone. Moreover, it can be applied even in the very complicated instances of the GLPC systems with heterogeneous, and in addition not totally loaded, support surfaces. The utility of this method is demonstrated for two different GLPC systems with strong adsorption properties.

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