𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Investigations into the regioselective deuteriation of enolates derived from silyl enol ethers and enolacetates

✍ Scribed by Gregory S. Coumbarides; Jason Eames; Neluka Weerasooriya


Publisher
John Wiley and Sons
Year
2001
Tongue
French
Weight
127 KB
Volume
44
Category
Article
ISSN
0022-2135

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Results are reported on the regioselective C‐deuteriation of a series of enolates derived from the addition of MeLi to the related enolacetate and silyl enol ether and discussed in terms of the similarity between these methods; comments are made on the possible role of the additive, lithium tert‐butoxide. Copyright © 2001 John Wiley & Sons, Ltd.


📜 SIMILAR VOLUMES


Investigations into the C-deuteriation o
✍ Svitlana Buksha; Gregory S. Coumbarides; Marco Dingjan; Jason Eames; Michael J. 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 French ⚖ 188 KB

Results are reported on the regioselective C-deuteriation of a series of silyl enol ethers derived from aryl alkyl ketones using deuterium (D 2 ) gas as the deuterium source and palladium-on-barium sulfate as the mediator. These results highlight the numerous reaction pathways and different product

Investigations into the regioselective C
✍ Gregory S. Coumbarides; Jason Eames; Neluka Weerasooriya 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 French ⚖ 125 KB

## Abstract Results are reported on the regioselective __C__‐deuteriation of 2‐methyl tetralone using a series of diisopropylamine derived __D__‐sources. The results presented further aid the understanding of kinetic deuteriation of both ‘base‐containing’ and ‘base‐free’ enolates. Copyright © 2002

Investigations into the C-deuteriation o
✍ Svitlana Buksha; Gregory S. Coumbarides; Marco Dingjan; Jason Eames; Michael J. 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 French ⚖ 176 KB

Results are reported on the regioselective C-deuteriation of a series of enol acetates (derived from the aryl alkyl ketones) using molecular deuterium as the D-source and palladium-on-barium sulphate as the mediator. The results presented highlight potential problems associated with the deuteriation

Investigations into the regioselective C
✍ Gregory S. Coumbarides; Jason Eames; Michael J. Suggate 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 French ⚖ 150 KB

## Abstract Results are reported on the regioselective __C__‐deuteriation of 2‐methyl tetralone using piperidine‐__d__~11~ as a deuterium source. The results presented further aid the understanding of kinetic deuteriation of amine–enolate complexes. Copyright © 2004 John Wiley & Sons, Ltd.