## Abstract Results are reported on the regioselective __C__‐deuteriation of 2‐methyl tetralone using a series of diisopropylamine derived __D__‐sources. The results presented further aid the understanding of kinetic deuteriation of both ‘base‐containing’ and ‘base‐free’ enolates. Copyright © 2002
Investigations into the regioselective C-deuteriation of enolates derived from 2-methyl tetralone using piperidine-d11
✍ Scribed by Gregory S. Coumbarides; Jason Eames; Michael J. Suggate
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- French
- Weight
- 150 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0022-2135
- DOI
- 10.1002/jlcr.822
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✦ Synopsis
Abstract
Results are reported on the regioselective C‐deuteriation of 2‐methyl tetralone using piperidine‐d~11~ as a deuterium source. The results presented further aid the understanding of kinetic deuteriation of amine–enolate complexes. Copyright © 2004 John Wiley & Sons, Ltd.
📜 SIMILAR VOLUMES
Results are reported on the regioselective C-deuteriation of 2-methyl-tetralone using a series of D-sources and tertiary amines as potential mediators. The results presented further aid the understanding of kinetic deuteriation of both 'base-containing' and 'base-free' enolates.
## Abstract Results are reported on the regioselective __C__‐deuteriation of a series of enolates derived from the addition of MeLi to the related enolacetate and silyl enol ether and discussed in terms of the similarity between these methods; comments are made on the possible role of the additive,