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Probing the regioselective C-deuteriation of lithium enolates derived from 2-methyl-tetralone in the presence of substituted tertiary amines

✍ Scribed by Mothia Begum; Sameer Chavda; Gregory S. Coumbarides; Marco Dingan; Jason Eames; Michael J. Suggate; Neluka Weerasooriya

Publisher
John Wiley and Sons
Year
2006
Tongue
French
Weight
213 KB
Volume
49
Category
Article
ISSN
0022-2135

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✦ Synopsis

Results are reported on the regioselective C-deuteriation of 2-methyl-tetralone using a series of D-sources and tertiary amines as potential mediators. The results presented further aid the understanding of kinetic deuteriation of both 'base-containing' and 'base-free' enolates.

📜 SIMILAR VOLUMES

Investigations into the regioselective C
Investigations into the regioselective C-deuteriation of enolates derived from 2-methyl tetralone using piperidine-d11
✍ Gregory S. Coumbarides; Jason Eames; Michael J. Suggate 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 French ⚖ 150 KB

## Abstract Results are reported on the regioselective __C__‐deuteriation of 2‐methyl tetralone using piperidine‐__d__~11~ as a deuterium source. The results presented further aid the understanding of kinetic deuteriation of amine–enolate complexes. Copyright © 2004 John Wiley & Sons, Ltd.