## Abstract Results are reported on the regioselective __C__‐deuteriation of 2‐methyl tetralone using piperidine‐__d__~11~ as a deuterium source. The results presented further aid the understanding of kinetic deuteriation of amine–enolate complexes. Copyright © 2004 John Wiley & Sons, Ltd.
Investigations into the regioselective C-deuteriation of enolates using a diisopropylammonium salt
✍ Scribed by Gregory S. Coumbarides; Jason Eames; Neluka Weerasooriya
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- French
- Weight
- 125 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0022-2135
- DOI
- 10.1002/jlcr.615
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✦ Synopsis
Abstract
Results are reported on the regioselective C‐deuteriation of 2‐methyl tetralone using a series of diisopropylamine derived D‐sources. The results presented further aid the understanding of kinetic deuteriation of both ‘base‐containing’ and ‘base‐free’ enolates. Copyright © 2002 John Wiley & Sons, Ltd.
📜 SIMILAR VOLUMES
## Abstract Results are reported on the regioselective __C__‐deuteriation of a series of enolates derived from the addition of MeLi to the related enolacetate and silyl enol ether and discussed in terms of the similarity between these methods; comments are made on the possible role of the additive,
Results are reported on the regioselective C-deuteriation of a series of enol acetates (derived from the aryl alkyl ketones) using molecular deuterium as the D-source and palladium-on-barium sulphate as the mediator. The results presented highlight potential problems associated with the deuteriation
Results are reported on the regioselective C-deuteriation of a series of silyl enol ethers derived from aryl alkyl ketones using deuterium (D 2 ) gas as the deuterium source and palladium-on-barium sulfate as the mediator. These results highlight the numerous reaction pathways and different product