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Intramolecular relaxation of vibrational energy in alkyl radicals

โœ Scribed by B.S. Rabinovitch; A.B. Trenwith

Publisher
Elsevier Science
Year
1981
Weight
143 KB
Volume
17
Category
Article
ISSN
0047-2670

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๐Ÿ“œ SIMILAR VOLUMES

Intramolecular vibrational energy relaxa
Intramolecular vibrational energy relaxation in benzene
โœ Paul J. Nagy; William L. Hase ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 294 KB

Preliminary results arc reported of a Monte Carlo trajectory study of intramolecular vibrational ener\_w relaxation in a model of benzene. Very little relaxation 1s found to occur on d picosecond timeswle. The rate of intramolecular wbrational energy relaxation appears to be dependent upon the natur

Intramolecular vibrational relaxation in
Intramolecular vibrational relaxation in the 3-methyl-3 hexyl radical
โœ S.P. Wrigley; B.S. Rabinovitch ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 523 KB

Vibrational energy relasation has been measured at Hz bath gas pressures from 1 lo 65000 Torr at 298 K in the competitive channel decomposition of 3-methyl-3-hexyl radicals chemically activated to ~44 kcal mol-I. Decomposition of the initially formed, internally non-randomized ndiuls occurs on a pic

Intramolecular relaxation of phenyl-alky
Intramolecular relaxation of phenyl-alkyl ketones
โœ M.A. Mazid; S. Walker; N.A. Weir ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science โš– 552 KB

Dielectric absorption studies have been made (with one exception) in the ranges ED-280K and IO\*-IO5 Hz of eight ketones of the type C6H5COR where R is varied from CH3 to C10H2, in a polystyrene matrix. An intramolecular relaxation process has been found in each case with an enthalpy of activation o