The rotational-temperature dependence of the energy-resolved fluorescence, combined with the calculated level density, indicates that the large variations in the rate of the intramolecular vibrational relaxation over a small escess energy in Sr pcrylene is due to the fluctuations in the density of a
Intramolecular relaxation of excess vibrational energy in jet-cooled perylene
β Scribed by Steven A. Schwartz; Michael R. Topp
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 1022 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0301-0104
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We report the observation of quantum interference effects in the energy-resolved fluorescence decays of the second excited singlet state ofjet-cooled azulene. The results are analyzed and discussed in terms of a real-time view of intramolecular vibrational relaxation.
Here \Le report on the ducct obscrvatron of ttme-resolved iormarion of a product of mtr~molecuLu cncrgy rnnsicr III rsolaIrd,Jct~ooled A\*-CHz-CH2-CHz -B The anthncrne chromophorc (A) u'as cwitcd bs plcosccond pulses, snd the transfer o~cncrgy was probed BI vmous cwess cnergics by obvrmg the emwon a