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Intramolecular radical coupling of a phenolic enolate: Oxidative fragmentation of the spirodiketone intermediate

โœ Scribed by A. Leboff; A.-C. Carbonnelle; J.-P. Alazard; C. Thal; A.S. Kende

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
134 KB
Volume
28
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Ferricynnide oxidation of the dianion of the pbenolic B-diketone 6b in basic conditions effects intramolecular radical coupling to form the spirocyclic diketone I which leads to the hydroxy tetralone 8 via an oxidative fragmentation process. _ Reactions in Steroid Chemistry",

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