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Intersystem crossing in anthracene-N,N-diethylaniline exciplex

✍ Scribed by Takashi Nishimura; Nobuaki Nakashima; Noboru Mataga

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
400 KB
Volume
46
Category
Article
ISSN
0009-2614

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✦ Synopsis

T&c growing-in of the anthraccnc triplet state has been mcasurcd in the cast of the anthracenc-NJUN-dicthylanthnc cxciplex system in hcxane. The anthracenc triplet state IS formed from the relaxed cxciplcv fluorescent state.

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A trnnsicnt absorption is observed in nnthraccne (A/-N, N-diethyianiline (D) sofutions in toiuene excited by the 3371k line of n nitrogen laser. The lifetime of the transient matches that of the fluorescence of the excited (DA) charge transfer complex. The absorption is assigned to a transition from