✦ LIBER ✦

Resonances in mediated intersystem crossing of jet-cooled anthracene derivatives

✍ Scribed by Aviv Amirav; Joshua Jortner

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 646 KB
Volume: 132
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80621-2

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✦ Synopsis

The major jR#g~a~ eIemnic ~l~a~~~ mrxkaaism from the first el~t~Rj~ly excited St singleE manifold of anthracene and its isotopic and chemical derivatives involves intersystem crossing (ISC) [ 1-15 1, which proceeds via two parallel mechanisms:

(1) DirectSi-+ ISC [Sj to thestatistical first triplet manifbid. The direct ISC rate is

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