Photoinduced electron-transfer reaction of anthracene with N,Ndiethylaniline (DEA) was studied in the SDS (sodium dodecyl sulfate)/BA (benzyl alcohol)/H 2 O system. In an oil/water microemulsion, only the excited anthracene located at the interface can be quenched by DEA. In a water/oil microemulsio
Fluorescence quenching of anthracene by N, N-diethylaniline in the O/W microemulsion
✍ Scribed by Xia Guo; Hui Xu; Rong Guo
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 455 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0256-7660
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✦ Synopsis
Abstract
Photoinduced electron‐transfer system of anthracene‐N, N‐diethylaniline (MA) was studied in the oil in water (O/W) microemulsions formed by SDS (sodium dodecyl sulfate), BA (benzyl alcohol) and H~2~O. The time‐resolved fluorescence study showed mat the fluorescence quenching of the excited anthracene by DEA occurs at the interface of the O/W microemulsions. Besides as the quencher of the excited anthracene, N, N‐diethylaniline could act as a cosurfactant to change the structures of the microemulsions, Just as BA did. The quenching rate constants for the different structures of the system were determined.
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