Excited singlet-singlet absorption spectra of aromatic charge-transfer complexes have been recorded using pulsed-laser excitation. The spectra (obtained for the tetracyanobenzene-toluene, tetracyanobenzene-benzene and pyromellitlcdianhydride-mesitylene systems) are practically identical with those o
Excited singlet-singlet spectra of anthracene, N,N-diethylaniline and their CT complex
โ Scribed by Chmouel R. Goldschmidt; Michael Ottolenghi
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 319 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
A trnnsicnt absorption is observed in nnthraccne (A/-N, N-diethyianiline (D) sofutions in toiuene excited by the 3371k line of n nitrogen laser. The lifetime of the transient matches that of the fluorescence of the excited (DA) charge transfer complex. The absorption is assigned to a transition from the fluorescent CT state to a higher CT singlet of the complex. Excited singlet-singlet absorptions nre also observed fox the free anthracene and Zi, N-diethylani~jne molecules.
๐ SIMILAR VOLUMES
The excited singlet-singlet absorption spectra of s-tetracyaobenzene (TCNB) complexes with toluene and benzene were observed. The spectra were obtnined using the re-absorption of the CT fluorescence by the fluorescent EDA complexes produced densely by means of the excitation with a giant pulse Iaser
## Abstract The electronic absorption spectrum of anthraceneโ9,10โendoperoxide (APO) has been investigated by means of multiconfigurational multiโstate second order perturbation theory on complete active space selfโconsistent field wavefunctions (MSโCASPT2/CASSCF) and two single reference methods:
Changes in dielectric loss at microwave frequencies resulting from UV laser excitation of solutions of 4-N,N-dimethyfaminobsnzonitrile and some of its derivatives in cyclohexane and in lfl-dioxane have been studied. The changes are due to differences between the dipole moments of the sohste in the g