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Internal motion of the cyclopentyl radical in CF2ClCFCl2: An ESR investigation

✍ Scribed by L. Sjöqvist; M. Lindgren; A. Lund

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
367 KB
Volume
156
Category
Article
ISSN
0009-2614

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✦ Synopsis

The internal motion of the cyclopentyl radical, trapped in a halocarbon matrix, CF,ClCFCI,, has been studied utilizing electron spin resonance (ESR) spectroscopy. The lineshapes of the ESR spectra corresponding to the radical exhibit an alternating linewidth effect in the temperature range 1 lo-135 K. The experimental ESR spectra were simulated using a dynamical model based on interconversion between two twisted C2 structures and the activation energy was estimated to 2.8 kcal/mol.

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