ESR study of internal rotation in the isopropyl phenyl nitroxide radical
✍ Scribed by L. Jókay; A. Rockenbauer; P. Simon; F. Túdós
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 398 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0022-2860
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📜 SIMILAR VOLUMES
Information on the rotational motion of various types of spin-labelled long-chain nitroxides was obtained from the anisotropic ESR signals. By varying the position of the nitroxide moiety along the chain, the intrinsic flexibility of molecular chain was examined. The rotational correlation times (t,
## Abstract Various __N__‐nitrosamines were photolyzed in toluene solution in the temperature range −100°C to −30°C to yield dialkyl nitroxides. The nitrosamines studied were __N__‐nitrosodimethylamine, __N__‐nitrosodiethylamine, __N__‐nitrosodipropylamine, __N__‐nitrosodibutylamine and __N__‐nitro