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ESR study of the conformation of nitroxide free radicals

✍ Scribed by A. Rockenbauer; S.A. Abdel-Monem; G. Móger; L. Sümegi


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
490 KB
Volume
46
Category
Article
ISSN
0022-2860

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ESR Study of Nitroxide Radicals Generate
✍ Ladislav Omelka; Imrich Vrábel; Katarína Erentová; Jochen Dauth; Bernward Deubze 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 German ⚖ 410 KB

The triazenols 4-R1-C6H4-N=N-N(OH)-R2 (l), oxidized with t-BuO; radicals, produced nitroxide radicals R'-C6H4-N(O')-N=N(R2)+0- (5). The suggested radical structure was confirmed by "N-labeling. The reaction of triazenols 1 with PbO, proceeded under N2 elimination, in which case nitroxides R'-C6H4-N