Photoelectron spectra studies of organic free radicals. The nitroxide radical
β Scribed by Isao Morishima; Kenichi Yoshikawa; Teijiro Yonezawa; H. Matsumoto
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 360 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
## He(I) photoelectron spectra of the hydroxyl radical show ionizations corresponding to the production of OH\* (CID+) in the states X32-and 'A at ionization potentials of 13.01 eV and 15.20 eV respectively. The excitation energy of the \*A state is in very good agreement with that predicted by ca
A nv.~.dif~Β’d mttltiplc reflt.'dion sysl.cm in ',.vhich the image of the source is focused into lhe flame in,/.tcad or on I.o the mirrm surlaΒ’cs has been devulolxd. It reduces troubles due to defocusing of the lighl beam by refraelive index gr:tdit, ms in IhΒ’ ll,,me and gives belter sp~ltial resolut
To aidin inteqreting fhe experimental ionizati& potekials CNDO/Z calculatiox~~ gere cassied out asuming that-the ion had the. same geometry as the paren/ free radical. These caIcuI.atio~~ .&owed that theeIectron confiition for ClO, is . ..G b:a: pi: and for ClO; is . ..a. b: 4 with the lowest unoccu