The photoelectron spectra of the OH and OD radicals
โ Scribed by S. Katsumata; D.R. Lloyd
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 264 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
He(I) photoelectron
spectra of the hydroxyl radical show ionizations corresponding to the production of OH* (CID+) in the states X32-and 'A at ionization potentials of 13.01 eV and 15.20 eV respectively. The excitation energy of the *A state is in very good agreement with that predicted by calculations and experiment; vibrational spacings in the X 'Z-state agree with emission spectroscopic data.
๐ SIMILAR VOLUMES
The high-resolution He 584 A photoelectron spectra of ten diuanaphthalenes are presented. The ordering of the n orbit& and the nitrogen "lone-pair" orbitals is discussed. Several semi-empirical quantum-chemical calculation methods have been screened against the esperimentd evidence.