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Molecular motion of the radical cations in the condensed phase as studied by ESR: Diazabenzenes

✍ Scribed by Michio Matsushita; Takamasa Momose; Tatsuhisa Kato; Tadamasa Shida

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
401 KB
Volume
161
Category
Article
ISSN
0009-2614

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✦ Synopsis

The radical cation of three diazabenzenes, pyridaxine, pyrimidine, and pyrazine, have heen investigated by ESR in the temperature region of 6-I43 K. The observed spectra changes have been analyzed by the density matrix method with a model of uniaxial rotation of the radicals. A conspicuous difference in the dynamical behavior of the three similar systems is found.

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