Hydrozirconation and hydrostannation, together with Pdo catalysed coupling, are used to make (2E,4Z,6E)-, (2E,4E,6E)-and (2E,4E,GZ)-tetraenol stems as synthetic intermediates for synthesis of the AK-II, AF-llc, AF -Ila host-selective plant toxins.
β¦ LIBER β¦
Insecticidal amides. Synthesis of natural 2(E),4(E),10(E)-pipercide, its 2(E), 4(E), 10 (Z)- stereomer, and related isobutylamides
β Scribed by Leslie Crombie; Raynond Denman
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 222 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
Natural [all (lJ)
]pipercide and its 2(E),4(E),lO(Z)-stereomer are synthesised, the latter having superior insecticidal potency and knock down. lO,ll-Dihydroand lO,ll-dehydropipercides are also prepared.
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