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One-Pot synthesis of (2E)- and (2E, 4E)- unsaturated carboxylic acid amides via organotellurium reagents

✍ Scribed by Wen-Juan Xiao; Li-Lan Shi; Zheng-Qing Chen; Yao-Zeng Huang; S. A. Lang

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
395 KB
Volume
1
Category
Article
ISSN
1042-7163

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✦ Synopsis

Di-n-butyl telluride, 2-bromoacetylisobutylamide (or 2-bromoacetylpiperidide) react directly with saturated or +unsaturated aldehydes at room temperature in the presence of potassium carbonate(s) to afford (2E)-, or (2E, 4E)-unsaturated carboxylic acid amides, respectively, in excellent yields with high E stereoselectivity .

πŸ“œ SIMILAR VOLUMES

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