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2- and 8- functionalized 1,4,7,10-tetraoxaspiro[5.5]undecanes. I. Synthesis of (±)-E,E and (±)-Z,E structures.

✍ Scribed by Marielle Lemaire; Georges Jeminet; Jean-Gabriel Gourcy; Gérard Dauphin

Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
559 KB
Volume
49
Category
Article
ISSN
0040-4020

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2- and 8- functionalized 1,4,7,10-tetrao
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The first syntheses of the novel [1,2]thiaphospholo[4,5-e][1)2,4]triazine ring system, exemplified by the derivatives 3a-c have been accomplished by the action of Lawesson's reagent on the 5-arylmethyl-l,2,4-triazin-6-ones la-¢, their thiones 2a-c or the Mannich bases 4-6. The structure of these new