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Synthesis of the (2E,4Z,6E)-, (2E,4E,6E)- and (2E,4E,6Z)-tetraenol stems of the host-selective AK and AF toxins by hydrometallation

✍ Scribed by Leslie Crombie; Mark A Horsham; Sandra R.M Jarrett

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 192 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80715-2

No coin nor oath required. For personal study only.

✦ Synopsis

Hydrozirconation and hydrostannation, together with Pdo catalysed coupling, are used to make (2E,4Z,6E)-, (2E,4E,6E)-and (2E,4E,GZ)-tetraenol stems as synthetic intermediates for synthesis of the AK-II, AF-llc, AF -Ila host-selective plant toxins.

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