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ChemInform Abstract: Stereospecific Preparation of (1E,3E,5E)-3,4-Difluoro-1,6-diphenylhexatriene (III) and (2E,4E,6E)-Diethyl-4,5-difluoroocta-2,4,6-trienedioate (V).

✍ Scribed by Qibo Liu; Dale C. Swenson; Donald J. Burton


Publisher
John Wiley and Sons
Year
2011
Weight
27 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereospecific Synt
✍ S. N. DENISENKO; P. RADEMACHER; R. G. KOSTYANOVSKY πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 1 views

## Stereospecific Synthesis of Bicyclic Diaziridines: 4a-Chloro-; 4e,6a-and 4a,6e-Dichloro-5-methoxycarbonyl-1,6diazabicyclo[3.1.0]hexanes. -Amination of 3-chloro-1-pyrroline (I) with H 2 N-O-SO 3 H occurs predominantly from the anti side with respect to chlorine to afford diaziridine (II). Chlor