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Initiator-Fragment Incorporation Radical Polymerization of Divinyl Adipate with Dimethyl 2,2‘-Azobis(isobutyrate): Kinetics and Formation of Soluble Hyperbranched Polymer

✍ Scribed by Sato, Tsuneyuki; Arima, Yukiko; Seno, Makiko; Hirano, Tomohiro


Book ID
127129444
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
219 KB
Volume
38
Category
Article
ISSN
0024-9297

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Formation of Soluble Hyperbranched Polym
✍ Tomohiro Hirano; Hiroshi Ihara; Takashi Miyagi; Hongwei Wang; Makiko Seno; Tsune 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB

## Abstract **Summary:** Ethylene glycol dimethacrylate (**1**) was polymerized at 70 and 80 °C in benzene using high concentrations of the initiator, dimethyl 2,2′‐azobisisobutyrate (**2**). When the concentrations of **1** and **2** were 0.10 and 0.50 mol · L^−1^, respectively, the polymerization