## Abstract **Summary:** Ethylene glycol dimethacrylate (**1**) was polymerized at 70 and 80 °C in benzene using high concentrations of the initiator, dimethyl 2,2′‐azobisisobutyrate (**2**). When the concentrations of **1** and **2** were 0.10 and 0.50 mol · L^−1^, respectively, the polymerization
✦ LIBER ✦
Synthesis and characterization of soluble hyperbranched polymer via initiator-fragment incorporation radical polymerization of divinylbenzene with dimethyl 2,2′-azobisisobutyrate
✍ Scribed by Tomohiro Hirano; Naoki Higashida; Hongwei Wang; Makiko Seno Tsuneyuki Sato
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 228 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0021-8995
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## Abstract **Summary:** Soluble hyperbranched acrylate copolymers were prepared by the copolymerization of divinylbenzene (0.10 mol · L^−1^) and ethyl acrylate (0.50 mol · L^−1^) using dimethyl 2,2′‐azoisobutyrate of high concentrations (0.30–0.50 mol · L^−1^) as initiator at 70 and 80 °C in benze