𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reactivity of primary radicals in the radical polymerization of dialkyl fumarates initiated with dimethyl 2,2'-azobis(isobutyrate) and 2,2'-azobis(isobutyronitrile)

✍ Scribed by Yoshioka, Masahiro; Otsu, Takayuki


Book ID
126989925
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
476 KB
Volume
25
Category
Article
ISSN
0024-9297

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Initial Radical Separation after Photoly
✍ Antonβ€…N. Savitsky; Henning Paul; Anatolyβ€…I. Shushin πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 German βš– 148 KB

## Abstract There is a contradiction as to the initial spatial separation __r__~i~ of the two transient 2‐cyanoprop‐2‐yl radicals (Me~2~$\rm{{{\dot C}}}$ο£ΏCN) formed by flash photolysis of 2,2′‐azobis(isobutyronitrile) (AIBN) in solvents of various viscosities. The cage effect, expressed in terms of