Hyperbranched Polymer through Initiator-Fragment Incorporation Radical Copolymerization of Divinyl Adipate with Allyl Acetate: Synthesis, Characterization, Dye Solubilization, Metal-Nanoparticle Stabilization, and Porous Film Formation

Hyperbranched Acrylate Copolymer via Ini

Hyperbranched Acrylate Copolymer via Initiator-Fragment Incorporation Radical Copolymerization of Divinylbenzene and Ethyl Acrylate: Synthesis, Characterization, Hydrolysis, Dye-Solubilization, Ag Particle-Stabilization, and Porous Film Formation

✍ Tsuneyuki Sato; Hiroki Nobutane; Tomohiro Hirano; Makiko Seno 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 279 KB

## Abstract **Summary:** Soluble hyperbranched acrylate copolymers were prepared by the copolymerization of divinylbenzene (0.10 mol · L^−1^) and ethyl acrylate (0.50 mol · L^−1^) using dimethyl 2,2′‐azoisobutyrate of high concentrations (0.30–0.50 mol · L^−1^) as initiator at 70 and 80 °C in benze