Inhibition of the H2O2 reaction by CF3Cl
✍ Scribed by Yoshiaki Hidaka; Hiroyuki Kawano; Masao Suga
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 186 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0010-2180
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A relative rate approach has , been used to measure the reactivity of CF,O radicals towards ozone. Using k(CFaO+NOa)=2,7x IO-" cm' molecule-' s-' as the referencereactioqanupperlimit ofk(CF,O+Os) 63~ 10-'4cmSmolecule-' was determined at 295 K and 700 Torr of O2 diluent. The implications for the atmo
Flash photolysis/time-resolved UV absorption measurements of the rate constants for the title reactions are reported over the temperature range 2 lo-253 K. The photolysis of F2/CF,H/03/02/N, gas mixtures reveals that the formation of CF302 and CF,O radicals has no measurable effect on the ozone conc