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The reaction of CF3Cl and H2 in shock waves

✍ Scribed by Yoshiaki Hidaka; Kazuyuki Kawanami; Hiroyuki Kawano; Masao Suga


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
459 KB
Volume
103
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES


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CFaBr-Hz mixtures highly diluted with Ar were studied by using a time-resolved IRemission of HBr and a gas-chromatography for reaction products. The temperature range covered was 1000-1600 K and the total pressure behind the reflected shock waves used was 1.2-2.6 atm. CF3H, C#6, and CzF4 were produc

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The following reactions: (1, -1) . CF, + CzFSC1 CF&l + ' CzF5 (2) (3) were studied over the temperature ranges 533-687 K, 563-663 K, and 503-613 K for the forward reactions respectively and over 683-763 K, for the back reaction. Arrhenius parameters for chlorine atom transfer were determined re

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A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.