CFaBr-Hz mixtures highly diluted with Ar were studied by using a time-resolved IRemission of HBr and a gas-chromatography for reaction products. The temperature range covered was 1000-1600 K and the total pressure behind the reflected shock waves used was 1.2-2.6 atm. CF3H, C#6, and CzF4 were produc
The reaction of CF3Cl and H2 in shock waves
β Scribed by Yoshiaki Hidaka; Kazuyuki Kawanami; Hiroyuki Kawano; Masao Suga
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 459 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0009-2614
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The pyrolysis of CF,H mixture, highly diluted with Ar, was studied over the temperature range 1150-I 570 K at pressures 1.5-2.6 atm behind reflected shock waves. The mechanism and the rate constant of CFXH pyrolysis at the high temperatures were discussed. The pyrolysis of CFgH was found to be inter
The following reactions: (1, -1) . CF, + CzFSC1 CF&l + ' CzF5 (2) (3) were studied over the temperature ranges 533-687 K, 563-663 K, and 503-613 K for the forward reactions respectively and over 683-763 K, for the back reaction. Arrhenius parameters for chlorine atom transfer were determined re
A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.