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Infrared predissociation of (NO)2: Rotational distribution of the fragments

✍ Scribed by Ph. Briéchignac; N. Halberstadt; B.J. Whithaker; B. Coutant

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
385 KB
Volume
142
Category
Article
ISSN
0009-2614

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✦ Synopsis

An experiment to measure the product internal state distribution in the infrared predissociation of (NO)* (Y,,) has been performed, using (2 + 2) REMPI as the detection technique. The results show that a small amount of the excess energy is converted into rotation. Comparison with earlier data concerning photodissociation through the u, mode suggests that non-adiabatic transitions are the dominant mechanism in this predissociation.

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