The photodissociation spectrum of N: from 270 to 310 nm is broad and structureless at 300 K, with the cross section diminishing by a factor of 10 towards shorter wavelengths. We have detected fluorescence from N:(g) excited state fragments having quantum yield < 0.01 and risetime < 10 ns. The thresh
Rotational distribution of N2+ fragments from 355 nm photolysis of N4+
β Scribed by D. Lessen; S. Nizkorodov; P. Knupfer; T. Ruchti; E.J. Bieske; J.P. Maier
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 550 KB
- Volume
- 226
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The vibrational and rotational status of X 'xl N: fragments from the 355 nm photolysis of N: has been assessed using two complementary experimental techniques. Evidence from both methods suggests that the N$ photofragments are predominately in the u=O vibrational level of the electronic ground state and can possess considerable rotational energy (up to 3000 cm-r).
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