Microwave spectra of Ar-28 SiH 4 , Ar-29 SiH 4 , Ar-30 SiH 4 , and Ar-28 SiD 4 were recorded using a pulsed molecular beam Fourier transform microwave spectrometer. The K ϭ 0 and K ϭ 1 components of the J ϭ 3 4 2 through the J ϭ 7 4 6 transitions were measured and assigned in the 9 -24 GHz region. F
Rotational predissociation and libration in the infrared spectrum of ArHCl
✍ Scribed by B.J. Howard; A.S. Pine
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 679 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0009-2614
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A non-Markovian theory for the dipolar absorption coefficient of polar diatomic molecules diluted in a non-polar liquid medium is applied to obtain the far-infrared spectra of HCl in liquid Ar at densities between 480 and 100 amagat and T= 162.5 K. The time correlation functions involved in the theo
A hybrid quantum/semiclassical simulation method is applied to the photodissociation dynamics of HCI in the Ar-HCI cluster. The method treats the hydrogen quantum mechanically, and the heavy atoms by semiclassical wavepackets. The dynamics of the H atoms if found to show resonances where the H atom
The L 2,3-MM Auger spectra of HCI and Ar have been calculated. Strong interaction between the Auger diagram state 40~~ and correlation states explains the absence of the L ~,s-LM: peak in the HCl spectrum. For argon semi-internal CI reproduces the high-kinetic-energy redon, while 3. fairly large exp