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Influence of the dehydrochlorination rate on the degradation mechanism of poly(vinyl chloride)

✍ Scribed by Hjertberg, T.; Martinsson, E.; Soervik, E.

Book ID
126019009
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
887 KB
Volume
21
Category
Article
ISSN
0024-9297

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## Abstract A set of poly(vinyl chloride) samples were investigated with respect to their thermal stability. The dehydrochlorination rates were measured in nitrogen at 190Β°C by use of a very accurate, conductometric method. For all polymers studied, a significant molecular weight increase was obser

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The thermal degradation of poly(viny1 chloride) (PVC) was studied by following the rates of dehydrochlorination a t temperatures between 18OOC and 280Β°C in pure nitrogen and air flow. Iron oxide accelerates the elimination of hydrogen chloride from PVC. The accelerating effect depends on the concent