Determination of the Degradation Mechanism from the Kinetic Parameters of Dehydrochlorinated Poly(vinyl chloride) Decomposition
β Scribed by Jordan, K. J.; Suib, S. L.; Koberstein, J. T.
- Book ID
- 121211626
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 99 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0022-3654
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## Abstract A set of poly(vinyl chloride) samples were investigated with respect to their thermal stability. The dehydrochlorination rates were measured in nitrogen at 190Β°C by use of a very accurate, conductometric method. For all polymers studied, a significant molecular weight increase was obser
The thermal dehydrochlorination of model compounds of PVC has been investigated in the liquid phase in an inert atmosphere. Electrophilic catalysis and the effect of various solvents on this reaction have been studied. It has been found that the electron-accepting power of the reaction medium is the